Percent excess air means how much above the theoretical air is the actual reaction consuming. So you need to calculate both Air-Fuel ratios; real and theoretical and then compare them.
First, the real reaction air-fuel ratio: There are 22 mol of air for every 3.3 mol of fuel, so AFactual = 22/3.3 = 6.66
Now, the stoichiometric reaction: There are 5 mol of air per mol of fuel, so AFtheoretical = 5/1 = 5
So, how much more (percentage wise) is the real reaction consuming? excess air = (AFactual - AFtheoretical)/AFtheoretical = (6.66 - 5)/5 = 0.33 = 33%