The values listed under "Average Power Consumption (kW)" refer to the END of the respective time interval. However, the "Max Demand" values refer to the START of the respective time interval. And remembering that in this context, "max demand" refers to maximum average demand measured in any single time interval, NOT the instantaneous maximum value measured.
Max demand at the start of interval #1 = 35 kW (given in the problem statement; we don't necessarily need to know how this number was obtained)
Max demand at the start of interval #2 = 35 kW (during interval #1, the average demand was only 25 kW, so the max demand registered did not change)
Max demand at the start of interval #3 = 37.5 kW (during interval #2, the average demand was 37.5 kW, so the new max demand registered is now 37.5 kW)
Max demand at the start of interval #4 = 62.5 kW (during interval #3, the average demand was 62.5 kW, so the new max demand registered is now 62.5 kW)
Max demand at the start of interval #5 = 62.5 kW (during interval #4, the average demand was 50 kW, so the max demand registered is still 62.5 kW)
Finally, the problem statement asks for the maximum demand registered at t=60 min, which is at the END of interval #4 and the START of interval #5.